Chromium, 24 Cr Metallic, reflective crystals of chromium metal and a cube of the same material Appearance silvery metallic
Atomic number (Z ) 24 Group group 6 Period period 4 Block d-block Electron configuration [Ar ] 3d5 4s1 Electrons per shell 2, 8, 13, 1 Phase at STP solid Melting point 2180 K (1907 °C, 3465 °F) Boiling point 2944 K (2671 °C, 4840 °F) Density (at 20° C) 7.192 g/cm3 [ 3] when liquid (at m.p. ) 6.3 g/cm3 Heat of fusion 21.0 kJ/mol Heat of vaporization 347 kJ/mol Molar heat capacity 23.35 J/(mol·K) Vapor pressure
P (Pa)
1
10
100
1 k
10 k
100 k
at T (K)
1656
1807
1991
2223
2530
2942
Oxidation states common: +3, +6
−4,[ 4] −2,[ 5] −1,[ 5] 0,[ 6] +1,[ 5] +2,[ 5] +4,[ 5] +5[ 5] Electronegativity Pauling scale: 1.66 Ionization energies 1st: 652.9 kJ/mol 2nd: 1590.6 kJ/mol 3rd: 2987 kJ/mol (more ) Atomic radius empirical: 128 pm Covalent radius 139±5 pm Color lines in a spectral range Spectral lines of chromiumNatural occurrence primordial Crystal structure body-centered cubic (bcc) (cI2 ) Lattice constant a = 288.49 pm (at 20 °C)[ 3] Thermal expansion 4.81× 10−6 /K (at 20 °C)[ 3] Thermal conductivity 93.9 W/(m⋅K) Electrical resistivity 125 nΩ⋅m (at 20 °C) Magnetic ordering antiferromagnetic (rather: SDW )[ 7] Molar magnetic susceptibility +180.0× 10−6 cm3 /mol (273 K)[ 8] Young's modulus 279 GPa Shear modulus 115 GPa Bulk modulus 160 GPa Speed of sound thin rod 5940 m/s (at 20 °C) Poisson ratio 0.21 Mohs hardness 8.5 Vickers hardness 1060 MPa Brinell hardness 687–6500 MPa CAS Number 7440-47-3 Naming from the Greek χρῶμα, "color", because many chromium compounds are intensely colored Discovery and first isolationLouis Nicolas Vauquelin (1794, 1797)
Main isotopes[ 9]
Decay
50 Cr
4.34%
stable
51 Cr
synth
27.7015 d
ε
51 V
52 Cr
83.8%
stable
53 Cr
9.50%
stable
54 Cr
2.37%
stable
File:Symbol category class.svg Category: Chromium | references
child table, as reused in {IB-Cr}
Main isotopes[ 9]
Decay
50 Cr
4.34%
stable
51 Cr
synth
27.7015 d
ε
51 V
52 Cr
83.8%
stable
53 Cr
9.50%
stable
54 Cr
2.37%
stable
References
These references will appear in the article, but this list appears only on this page.
↑ "Standard Atomic Weights: Chromium" . CIAAW . 1983.
↑ Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; Böhlke, John K.; Chesson, Lesley A.; Coplen, Tyler B.; Ding, Tiping; Dunn, Philip J. H.; Gröning, Manfred; Holden, Norman E.; Meijer, Harro A. J. (2022-05-04). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)" . Pure and Applied Chemistry . doi :10.1515/pac-2019-0603 . ISSN 1365-3075 .
↑ 3.0 3.1 3.2 Arblaster, John W. (2018). Selected Values of the Crystallographic Properties of Elements . Materials Park, Ohio: ASM International. ISBN 978-1-62708-155-9 .
↑ Cr(–4) is known in Na4 Cr(CO)4 ; see John E. Ellis (2006). "Adventures with Substances Containing Metals in Negative Oxidation States". Inorganic Chemistry . 45 (8): 3167– 3186. doi :10.1021/ic052110i .
↑ 5.0 5.1 5.2 5.3 5.4 5.5 Greenwood, Norman N. ; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann . p. 28. doi :10.1016/C2009-0-30414-6 . ISBN 978-0-08-037941-8 .
↑ Cr(0) is known in Cr(CO)6 ; see John E. Ellis (2006). "Adventures with Substances Containing Metals in Negative Oxidation States". Inorganic Chemistry . 45 (8): 3167– 3186. doi :10.1021/ic052110i .
↑ Fawcett, Eric (1988). "Spin-density-wave antiferromagnetism in chromium". Reviews of Modern Physics . 60 : 209. Bibcode :1988RvMP...60..209F . doi :10.1103/RevModPhys.60.209 .
↑ Weast, Robert (1984). CRC, Handbook of Chemistry and Physics . Boca Raton, Florida: Chemical Rubber Company Publishing. pp. E110. ISBN 0-8493-0464-4 .
↑ 9.0 9.1 Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF) . Chinese Physics C . 45 (3) 030001. doi :10.1088/1674-1137/abddae .
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